珠江口水体中铜与悬浮颗粒物相互作用的研究     

丘耀文  王肇鼎  张正斌  刘莲生 《热带海洋学报》1995,(4)

使用无机离子交换法研究珠江口水体中铜与悬浮颗粒物的相互作用，测出钢与悬浮颗粒物相互作用的ｐＨ曲线呈Ｓ形，其分级离子交换等温线是一种新的“台阶”型；从分级离子交换理论求得分级平衡常数Ｋ１为５．０，Ｋ２为７８．１，珠江口水体中铜的表观络合容量为０．９２μｍ及其条件稳定常数为３．５×１０７。  相似文献   

环渤海区域大气水份平衡特征的研究     

李爱贞  张富强  张桂芹  刘厚凤 《海洋科学》1996,20(5):29-34

利用１９８１￣１９９０年环渤海地区的地面气象资料，探空资料和土地利用资料，计算了该地区大气水份平衡方程中各分量，分析了其变化特征，并对它们之间的相互关系进行了研究。  相似文献   

黄河入海口壬基酚污染分布特征   总被引：2，自引：0，他引：2  

孙培艳  李正炎  王鑫平  崔文林  傅明珠 《海岸工程》2007,26(3):17-22

黄河口表、底层水体和沉积物中壬基酚的浓度分布特征研究结果表明,表层水体中壬基酚浓度为15.7~148.6 ng/L,平均值为47.5 ng/L;底层水体中壬基酚浓度为15.8~52.7ng/L,平均值为31.0 ng/L;表层沉积物中壬基酚浓度为2.31~5.47 ng/g,平均浓度为3.87ng/g。黄河口水体中壬基酚浓度呈现由河道向出海口外逐渐降低的趋势;河道中表层沉积物壬基酚含量高于出海口外。黄河口水体中壬基酚浓度低于文献中报道的海河口水体中的浓度,表层沉积物中壬基酚含量低于珠江口文献报道值。水体中壬基酚浓度超过抑制藤壶附着浓度(10 ng/L),河道最上游的站点水体中的浓度超过影响太平洋牡蛎幼苗的发育并增加幼苗死亡率的浓度(100 ng/L)。  相似文献   

Estuary/ocean exchange and tidal mixing in a Gulf of Maine Estuary: A Lagrangian modeling study   总被引：2，自引：0，他引：2  

Ata Bilgili  Jeffrey A. Proehl  Daniel R. Lynch  Keston W. Smith  M. Robinson Swift 《Estuarine, Coastal and Shelf Science》2005,65(4):607-624

A Lagrangian particle method embedded within a 2-D finite element code, is used to study the transport and ocean–estuary exchange processes in the well-mixed Great Bay Estuarine System in New Hampshire, USA. The 2-D finite element model, driven by residual, semi-diurnal and diurnal tidal constituents, includes the effects of wetting and drying of estuarine mud flats through the use of a porous medium transport module. The particle method includes tidal advection, plus a random walk model in the horizontal that simulates sub-grid scale turbulent transport processes. Our approach involves instantaneous, massive [O(500,000)] particle releases that enable the quantification of ocean–estuary and inter-bay exchanges in a Markovian framework. The effects of the release time, spring–neap cycle, riverine discharge and diffusion strength on the intra-estuary and estuary–ocean exchange are also investigated.The results show a rather dynamic interaction between the ocean and the estuary with a fraction of the exiting particles being caught up in the Gulf of Maine Coastal Current and swept away. Three somewhat different estimates of estuarine residence time are calculated to provide complementary views of estuary flushing. Maps of residence time versus release location uncover a strong spatial dependency of residence time within the estuary that has very important ramifications for local water quality. Simulations with and without the turbulent random walk show that the combined effect of advective shear and turbulent diffusion is very effective at spreading particles throughout the estuary relatively quickly, even at low (1 m²/s) diffusivity. The results presented here show that a first-order Markov Chain approach has applicability and a high potential for improving our understanding of the mixing processes in estuaries.  相似文献   

水库运行对漫湾库区洲滩水热交换影响          下载免费PDF全文

姬雨雨  陈求稳  施文卿  易齐涛  林育青 《水科学进展》2018,29(1):73-79

以澜沧江漫湾水库库区洲滩为研究对象,依据水库运行导致的水位波动特征,同步监测洲滩内部水位、水温变化过程,核算洲滩侧向潜流交换量,建立水温与水位之间的响应关系,分析潜流交换水流路径上溶解氧、溶解性碳素变化。结果表明:水库运行引起洲滩水位周期性波动,侧向潜流交换加强,洲滩水位最大变幅达2.2 m,水库一次蓄泄过程进出洲滩的水量达3 956 m^3,洲滩边缘区潜流交换量为中心区的4~5倍;在涨水过程中,洲滩水温下降,中底层温度梯度较大,而在落水过程中,洲滩水温上升,中表层温度梯度较大;溶解氧、溶解性有机碳和无机碳在河流至洲滩潜流交换路径上同步递减,分别从3.27 mg/L、7.3 mg/L和66.0 mg/L下降至0.17 mg/L、2.4mg/L和40.6 mg/L。水库运行导致的水位波动加强了库区洲滩潜流交换,对河流物质循环产生潜在影响。  相似文献   

安徽马鞍山市当涂地区地下水水化学特征及演化机制          下载免费PDF全文

李状  苏晶文  董长春  叶永红  杨洋 《中国地质》2022,49(5):1509-1526

【研究目的】 了解长江中下游平原地区地下水流系统并深入分析其地下水水化学特征及其演化机制。【研究方法】 综合马鞍山市当涂地区的水文地质条件、水动力场等,基于研究区水化学基本特征,运用多元统计分析、水化学图件、离子比值和反向水文地球化学模拟等方法对该地区浅层地下水水化学演化进行分析。【研究结果】 结果表明：（1）研究区地下水主要为低矿化度偏碱性水,地下水组分中阳离子以Ca²⁺和Mg²⁺为主,阴离子以HCO₃^-和SO₄^2-为主。（2）研究区地下水水化学类型主要可分为7类,其中松散岩类孔隙含水岩组和碎屑岩类孔隙裂隙含水岩组的水化学类型主要为HCO₃^-Ca型、HCO₃^-Ca·Na型、HCO₃·Cl-Ca·Na型以及HCO₃^-Ca·Mg型;基岩类裂隙含水岩组的化学类型主要为HCO₃·SO₄-Ca·Mg型和SO₄·HCO₃^-Ca·Mg型。（3）研究区浅层地下水水样超标率为46%,总体水质较差,超标率较高的组分依次为Mn、高锰酸盐指数（COD_Mn）、硝酸盐（以N计）、Fe、As、氨氮（以N计）等。（4）研究区地下水的化学组分主要受到岩石风化作用的控制;此外,还存在Na-Ca的正向阳离子交替吸附作用。反向水文地球化学模拟结果进一步定量论证了水岩相互作用对本区浅层地下水组分的形成和演化起着主导作用。【结论】 研究区地下水主要为低矿化度偏碱性,主要可分为松散岩类孔隙水、碎屑岩类孔隙裂隙水和基岩类裂隙水。主要离子比例和反向水文地球化学模拟揭示了本区浅层地下水化学组分主要是地下水溶滤方解石、白云石等碳酸盐矿物、石英、长石等硅酸盐矿物,高岭土等黏土矿物以及岩盐、石膏等达到过饱和之后形成的。  相似文献   

地下水与地表水水量交换识别及交换量计算——以新汴河宿州段为例          下载免费PDF全文

束龙仓  宫荣  栾佳文  龚建师  陶小虎  赵贵章  陶月赞 《水科学进展》2022,33(1):57-67

为提高地下水与地表水交换量计算结果的准确性,本文利用水力联系、水头差、水温、氡-222、氢氧稳定同位素构建综合识别方法（HHTRO）,对新汴河宿州段地下水与地表水水量交换进行识别,并计算交换量。计算结果表明:研究河段单位河长地表水补给地下水的水量变化范围为8.69~366.82 m3/（d·m）,地下水补给地表水的水量变化范围为0.72~120.90 m3/（d·m）;研究河段左岸为地下水补给地表水,单位河长净补给量为45.26 m3/（d·m）;河段右岸为地表水补给地下水,单位河长净补给量为214.33 m3/（d·m）;研究河段地下水与地表水水量交换以地表水补给地下水为主,地表水补给地下水的比例为55.14%。本研究可推动地下水与地表水交换量计算方法的发展,为流域或区域水资源评价提供必要的理论方法。  相似文献   

Modelling river water temperature using deterministic,empirical, and hybrid formulations in a Mediterranean stream     

Rafael Marcé  Joan Armengol 《水文研究》2008,22(17):3418-3430

River water temperature is a common target of water quality models at the watershed scale, owing to its principal role in shaping biogeochemical processes and in stream ecology. Usually, models include physically‐based, deterministic formulations to calculate water temperatures from detailed meteorological information, which usually comes from meteorological stations located far from the river reaches. However, alternative empirical approaches have been proposed, that usually depend on air temperature as master variable. This study explored the performance of a semidistributed water quality application modelling river water temperature in a Mediterranean watershed, using three different approaches. First, a deterministic approach was used accounting for the different heat exchange components usually considered in water temperature models. Second, an empirical approximation was applied using the equilibrium temperature concept, assuming a linear relationship with air temperature. And third, a hybrid approach was constructed, in which the temperature equilibrium concept and the deterministic approach were combined. Results showed that the hybrid approach gave the best results, followed by the empirical approximation. The deterministic formulation gave the worst results. The hybrid approach not only fitted daily river water temperatures, but also adequately modelled the daily temperature range (maximum–minimum daily temperature). Other river water features directly dependent on water temperature, such as river intrusion depth in lentic systems (i.e. the depth at which the river inflow plunges to equilibrate density differences with lake water), were also correctly modelled even at hourly time steps. However, results for the different heat fluxes between river and atmosphere were very unrealistic. Although direct evidence of discrepancies between meteorological drivers measured at the meteorological stations and the actual river microclimate was not found, the use of models including empirical or hybrid formulations depending mainly on air temperature is recommended if only meteorological data from locations far from the river reaches are available. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

Experimental and computational validation and verification of the Stokes–Darcy and continuum pipe flow models for karst aquifers with dual porosity structure     

Xiaolong Hu  Xiaoming Wang  Max Gunzburger  Fei Hua  Yanzhao Cao 《水文研究》2012,26(13):2031-2040

In our previous study, we developed the Stokes–Darcy (SD) model was developed for flow in a karst aquifer with a conduit bedded in matrix, and the Beavers–Joseph (BJ) condition was used to describe the matrix–conduit interface. We also studied the mathematical well‐posedness of a coupled continuum pipe flow (CCPF) model as well as convergence rates of its finite element approximation. In this study, to compare the SD model with the CCPF model, we used numerical analyses to validate finite element discretisation methods for the two models. Using computational experiments, simulation codes implementing the finite element discretisations are then verified. Further model validation studies are based on the results of laboratory experiments. Comparing the results of computer simulations and experiments, we concluded that the SD model with the Beavers–Joseph interface condition is a valid model for conduit–matrix systems. On the other hand, the CCPF model with the value of the exchange parameter chosen within the range suggested in the literature perhaps does not result in good agreement with experimental observations. We then examined the sensitivity of the CCPF model with respect to the exchange parameter, concluding that, as has previously been noted, the model is highly sensitive for small values of the exchange parameter. However, for larger values, the model becomes less sensitive and, more important, also produces results that are in better agreement with experimental observations. This suggests that the CCPF model may also produce accurate simulation results, if one chooses larger values of the exchange parameter than those suggested in the literature. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Benthic nutrient recycling in shallow coastal waters of the Bohai Sea   总被引：3，自引：0，他引：3  

刘素美张经  陈洪涛T.Raabe 《中国海洋湖沼学报》2004,22(4):365-372

Sediment-water fluxes of N and P species in the Bohai Sea were investigated in September-October 1998 and April-May 1999. The benthic fluxes of nutrient species were determined by incubating sediment core samples with bottom seawater bubbled with air or nitrogen. NO^-2,NH4, dissolved organic nitrogen (DON) and phosphorus (DOP), total dissolved nitrogen (TDN) and phosphorus (TDP), and PO4^3- showed a net exchange flux from seawater to sediment, while NO^-3, dissolved inorganic nitrogen (DIN) and SiO3^2- were released from sediment to seawater in the Bohai Sea. Sediment-water nutrient exchange increases DIN and reduces the phosphorus load in the Bohai Sea. The release of silicate from sediment to overlying seawater reduces potential silicate limitation of primary production resulted from decrease of riverine discharge.The exchange flux of nutrients showed no obvious seasonal variation. The present study showed that the concentrations and composition of nutrients in the water column were affected by suspended sediment, and that not all the exchangeable phosphate in sediment could be released via sediment resuspension.  相似文献